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排序方式: 共有500条查询结果,搜索用时 562 毫秒
91.
Yuuya Fujisawa Takaaki Tsuda Shunsuke Hashimoto Takeshi Sugahara Kazunari Ohgaki 《Chemical engineering science》2012,68(1):660-662
Three-phase equilibrium (pressure–temperature) relation of hydrate+aqueous+fluid phases for the hydrogen (H2)+tetra-n-butyl phosphonium bromide (TBPB)+water ternary system was investigated in a temperature range of 281.90–295.94 K and a pressure range up to 170 MPa. The behavior of the three-phase coexisting curve indicates no structural transition in the present experimental region. The Raman spectra obtained in the H2+TBPB mixed semi-clathrate hydrate crystal reveal that H2 molecule occupies only small cage compartmentally and the TBPB molecule is encaged with a set of other large cages. 相似文献
92.
Yukihide Shiraishi Shunsuke Kobayashi Naoki Toshima 《Israel journal of chemistry》2012,52(10):908-916
Metal nanoparticles are now creating a new class of materials that are different from either conventional bulk materials or atoms, giving one of the smallest building blocks of matter. Metal nanoparticles have various properties based on high surface area and quantum size effects. Here we focus on the application of metal nanoparticles to liquid crystal displays, which is providing a new field in science and technology. The doping of nanoparticles into liquid crystal materials induces the modification of almost all of the physical properties of the liquid crystal, causing a reduction in the response time of liquid crystal displays. These techniques may be an alternative approach for improving the properties of liquid crystals other than chemical synthesis. 相似文献
93.
94.
Jain Gu Seonggon Lee Seunghwan Eom Hosung Ki Eun Hyuk Choi Yunbeom Lee Shunsuke Nozawa Shin-ichi Adachi Jeongho Kim Hyotcherl Ihee 《International journal of molecular sciences》2021,22(18)
The halogen elimination of 1,2-diiodoethane (C2H4I2) and 1,2-diiodotetrafluoroethane (C2F4I2) serves as a model reaction for investigating the influence of fluorination on reaction dynamics and solute–solvent interactions in solution-phase reactions. While the kinetics and reaction pathways of the halogen elimination reaction of C2H4I2 were reported to vary substantially depending on the solvent, the solvent effects on the photodissociation of C2F4I2 remain to be explored, as its reaction dynamics have only been studied in methanol. Here, to investigate the solvent dependence, we conducted a time-resolved X-ray liquidography (TRXL) experiment on C2F4I2 in cyclohexane. The data revealed that (ⅰ) the solvent dependence of the photoreaction of C2F4I2 is not as strong as that observed for C2H4I2, and (ⅱ) the nongeminate recombination leading to the formation of I2 is slower in cyclohexane than in methanol. We also show that the molecular structures of the relevant species determined from the structural analysis of TRXL data provide an excellent benchmark for DFT calculations, especially for investigating the relevance of exchange-correlation functionals used for the structural optimization of haloalkanes. This study demonstrates that TRXL is a powerful technique to study solvent dependence in the solution phase. 相似文献
95.
Kazuya Nakata Keizo Udagawa Donald A. Tryk Tsuyoshi Ochiai Shunsuke Nishimoto Hideki Sakai Taketoshi Murakami Masahiko Abe Akira Fujishima 《Materials Letters》2009,63(18-19):1628-1630
A photosensitive TiO2 thin film embedded with Ag nanoparticles has been prepared from a Ti(OBu)4–acetylacetone solution, containing dispersed Ag nanoparticles, by the sol–gel method. UV–visible absorption spectra showed that the thin film obtained has two absorption bands, characteristic of the acetylacetone chelate rings and plasmon resonance from Ag nanoparticles. After the irradiation of UV light, the absorption band from the chelate rings almost disappeared, ascribed to structural changes associated with dissociation of the chelate rings. The thin film after the UV irradiation exhibited a broad absorption band in the IR spectrum, indicating that a Ti–O–Ti network was formed in the thin film. HRTEM and EDX spectra revealed that Ag nanoparticles were present and dispersed in the TiO2 thin film. Micro-patterns of 50 μm dots have been fabricated by UV irradiation through a corresponding photomask, followed by leaching. 相似文献
96.
Naoki Dohi Yukimasa Matsuda Norihiro Itano Kazuhiro Shimizu Kimio Mineka Wa Yoshinorika Wase 《加拿大化工杂志》1999,77(5):786-792
Mixing in a boil-off mechanically stirred tank reactor with multiple impellers was examined. Power consumption and gas hold-up were measured in boiling water in a 0.2 m i.d. stirred tank reactor with three four-pitched blade downflow disk turbines. Vapour was generated from both the immersed ring heater and the impellers. At low vapour generation rates, vapour was mainly generated from the impellers rather than from the heater, whereas nucleation occurred at the heater instead of the impeller at higher vapour generation rates. The mechanical power consumption decreased due to vapour generation. The change in boiling-to-non-boiling mechanical power ratio with varying impeller rotational speed and boiling rate was complicated and not monotonous except at higher impeller speeds and boiling rates. The gas hold-ups increased with increasing vapour generation rate but were rather small as compared to those in cold gas dispersing systems. Empirical correlations for power consumption and gas hold-up in boiling liquids were developed using the present experimental data. 相似文献
97.
Shunsuke Tsukamoto Takao Namihira Douyan Wang Sunao Katsuki Hidenori Akiyama Eisaku Nakashima Akihiro Sato Yoshitaka Uchida Masami Koike 《Electrical Engineering in Japan》2001,134(4):28-35
There are several important environmental problems in the world. One of them is acid rain caused by combustion flue gases from thermal power plants, factories, and automobiles. Different kinds of gas discharges, such as surface discharge, dc and ac corona discharge, silent discharge, and electron beam controlled discharge, have been studied for the removal of NOx and SO2 from flue gases. The recent development of repetitive pulsed power generators gives the pulsed steamer corona discharges a chance of success in the removal of NOx and SO2. In this paper, the experimental results of NOx and SO2 removal by a repetitive pulse power generator are described. The actual flue gas at a thermal power plant was used. It is shown that about 90% of the NO was removed at a flow rate of 0.8 liters/min and a repetition rate of 7 pps. © 2001 Scripta Technica, Electr Eng Jpn, 134(4): 28–35, 2001 相似文献
98.
Koji Takano Shunsuke Matsuura Jiang Yan Junya Suehiro Masanori Hara 《Electrical Engineering in Japan》1999,127(4):18-28
The effect of a thin insulation film on breakdown phenomena in liquid nitrogen in the presence of thermally induced bubbles is investigated with a cylinder‐to‐plane electrode. Bubbles were produced by a heater mounted in the cylinder, which is partially covered with an insulation film. The results show that the film's effect on the breakdown voltage is insignificant until a pore is formed on the film by a previous breakdown, but it becomes substantial after pore formation. The reduction rate in breakdown voltage after the pore formation depends on the gap length and heater power. The minimum breakdown voltage drops to the magnitude of the breakdown voltage in the gaseous phase at normal boiling temperature. The breakdown mechanism is discussed on the basis of bubble observation and numerical calculation of suspended‐bubble motion. © 1999 Scripta Technica, Electgr Eng Jpn, 127(4): 18–28, 1999 相似文献
99.
Toshiaki Murai Hitoshi Hasegawa Shunsuke Fujiwara 《Electrical Engineering in Japan》1998,122(2):48-60
In the superconducting maglev system it is important to develop a non-contact on-board power source without environmental pollution such as noise and exhaust gases; therefore, inductive power collection (IPC), which utilizes a harmonic magnetic field generated by ground coils in EDS, is being studied. However, alteration to a null-flux EDS that has a high drag ratio reduces the power collecting capacity in the IPC system. In addition, power collecting coils are located on the cryostat of the superconducting coil (SC), so eddy currents at the cryostat also reduce the power collecting capacity. Therefore, an exclusive SC type that locates the exclusive SCs and IPC and power collecting coils so as to face the upper and lower coils of ground coils, respectively, is examined; but we aim to improve the conventional type. After analyzing the influence of eddy currents at the cryostat in detail and improving the composition of the power collecting coil and cryostat, we found that the conventional type has the same capacity as the exclusive SC type. In order to prove the above-mentioned result, we measured the induced voltage of the new-type coils in a test run at Miyazaki test track and confirmed the output of this IPC system in a full-scale synthetic bench test with a PWM converter and magnetic field simulator. © 1998 Scripta Technica. Electr Eng Jpn, 122(2): 48–60, 1998 相似文献
100.
Yida Liu Huie Zhu Akira Watanabe Shunsuke Yamamoto Tokuji Miyashita Masaya Mitsuishi 《应用聚合物科学杂志》2021,138(37):50947
As a result of the vast Young's moduli difference between an inorganic semiconducting channel and flexible substrates, flexible optoelectronic devices readily lose their functionality through material delamination and local fracturing, which lead to short-circuiting of devices. For this study, we synthesized a catechol-containing polysiloxane (CFPS) adhesive and applied it to ZnO nanoparticle (NP) assembly on plastic substrates for flexible UV detector applications. The 30 nm thick CFPS adhesive can anchor 70 nm thick ZnO NPs strongly through a coordination bond, thereby forming an ultra-stable ZnO NP channel layer. A peeling test of ZnO NP layer was conducted using transparent tape (Scotch®; 3 M Inc.). The ZnO NPs were firmly immobilized, reflecting the outstanding mechanical stability of CFPS adhesives. A UV detector also exhibited stable photo-response performance even after a thousand iterations of bending with 3 mm curvature radii. The result indicates the polycyclosiloxane-based flexible device as promising for wearable detector applications. 相似文献